CrossRef Competing interests The authors declare that they do not have any competing interests. Authors’ contributions AU, TR and HR have equal contribution to this
work and the manuscript. All authors read and approved the final JNK-IN-8 manuscript.”
“Background With advantages of high power density, low-operating temperature, and low emissions, proton exchange membrane fuel cells (PEMFCs) have become new electrical sources for transportable and stationary applications in recent years. There is no doubt that oxygen reduction reaction (ORR) in the AC220 datasheet cathode of PEMFCs is a key factor determining the cell performance. The ORR generally proceeds by two pathways [1]: the direct four-electron-transfer reduction of oxygen that produces H2O and the two-electron-transfer buy BIX 1294 reduction of oxygen yielding H2O2 which may be further reduced to H2O. Between them, the former route is an ideal
path. Therefore, it is imperative to find an efficient catalyst that can enhance the direct four-electron-transfer reduction of oxygen to give H2O, in order to improve the efficiency of PEMFCs. To date, carbon supported Pt and/or its alloys have been widely accepted to be the most active catalyst for ORR, but the high cost and limited resource of Pt greatly hinder the large-scale commercialization. Hence, the development of low cost, efficient and stable non-precious metal catalysts for ORR has become the goal of worldwide fuel cell people. In the last few decades, several types of non-precious metal ORR catalysts, including transition metal macrocyclic compounds [2, 3] and chalcogenides [4, 5], enzymatic catalysts [6], inorganic oxide composites [7], and conducting polymers or nitrogen containing catalysts [8–10], have been
Resveratrol explored and the heat-treated transition metal-based nitrogen-containing complexes [11–17], such as porphyrins, phthalocyanines, dibenzotetraazaannulenes, phenanthrolines, polypyrrole (PPy), triethylenetetramine chelate, tripyridyl triazine, have been considered to be the most promising alternate. Among them, PPy has been paid much more attention because of the porous structure, high surface area, high conductivity, easy synthesis and excellent environmental adaptability [18, 19]. It can be used as a carrier of transition metal in the nitrogen-containing complex catalysts, where the metal particles can be fixed on its surface and physically dispersed, the interaction between PPy and metal particles can work as efficient active site for ORR [20, 21]. Recent researches on transition metal-based PPy-containing catalyst Co-PPy/C [1, 10, 21, 22] have demonstrated promising ORR activity and durability with both electrochemical experiments and single-cell performance measurements. More work is needed, however, to identify the ORR mechanism, the actual ORR active site and the effects of preparation techniques/parameters on the catalytic performance of this kind of catalyst.